## Defining the Families
**Brass** = Copper + Zinc. Zinc is the primary alloying element, typically 5-40%. Lead (up to 3%) is often added for machinability.
**Bronze** = Copper + Tin, Aluminum, Silicon, or other elements (not zinc). Modern usage extends to aluminum bronzes (Cu-Al), silicon bronzes (Cu-Si), and phosphor bronzes (Cu-Sn-P).
## Key Grades Compared
| Property | C36000 (Free-Cutting Brass) | C95400 (Aluminum Bronze) |
|----------|----------------------------|-------------------------|
| Composition | 61.5Cu-35.5Zn-3Pb | 81Cu-11Al-4Fe-4Ni |
| UTS | 338 MPa | 620 MPa |
| Elongation | 25% | 12% |
| Machinability Rating | 100 (reference) | 60 |
## Corrosion Resistance
Bronzes generally outperform brasses in aggressive environments:
- **Seawater**: Aluminum bronze and tin bronze resist seawater attack far better than brasses, which are susceptible to dezincification (selective leaching of zinc). Brasses with less than 15% Zn or those inhibited with arsenic resist dezincification.
- **Ammonia**: Brasses are susceptible to stress corrosion cracking (season cracking) in ammonia-containing environments. Bronzes are generally immune.
- **Acids**: Phosphor bronzes and aluminum bronzes resist dilute sulfuric acid and many organic acids better than brasses.
## Machinability
Free-cutting brass C36000 is the machinability benchmark for all copper alloys (rated 100). The lead content forms tiny inclusions that break chips cleanly. Aluminum bronzes machine at approximately 60%, requiring carbide tooling due to abrasive aluminum oxide inclusions.
## Strength
Aluminum bronzes offer the highest strength in the copper alloy family. C95400 reaches 620 MPa tensile strength in the heat-treated condition, approaching some low-alloy steels. For applications requiring both copper-alloy corrosion resistance and structural strength, aluminum bronze is the clear winner.
## Cost
Brasses are generally less expensive than bronzes because zinc costs less than tin or aluminum (in alloy form). C36000 brass costs approximately 5-8 USD/kg. Aluminum bronze C95400 costs approximately 10-15 USD/kg.
## When to Choose Each
**Choose brass when**: Machinability is paramount (fittings, valves, screws), the environment is non-marine, formability is needed (deep drawing, stamping), or electrical conductivity matters. Plumbing fittings, musical instruments, and decorative hardware are classic brass applications.
**Choose bronze when**: The application involves seawater or corrosive chemicals, high strength is required, wear resistance matters (bearings, bushings, gears), or ammonia SCC is a concern. Marine propellers, pump impellers, and heavy-duty bearings are classic bronze applications.
Brass vs Bronze: Copper Alloy Showdown
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Brass is copper alloyed with zinc for machinability and formability. Bronze is copper alloyed with tin, aluminum, or silicon for strength and marine corrosion resistance. The choice depends on environment, strength needs, and manufacturing method.
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